Geralt is always reachable by the network. Unless it's an emergency, expect not to hear back for a few hours, if not a few days.
To talk to him in person, you'll need to be in Cadens or go to his domain, a snowy mountain fortress. Yard is open; doors are locked. If he isn't around, leave a delivery with the white wolf.
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But for the sake of your ailing heart, I'll leave word.
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[Grumble, grumble. Now that he knows you are safe, the worry is drying up and leaving him snippy.]
For such an effort of traveling so far afield for your ingredients, I am now expecting something particularly delicious, I will have you know.
[Well. Not too snippy that he cannot still flirt from afar.]
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I'd hate to let you down.